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Total synthesis of Hinokione:
Reference: Snitman, D. L.; Himmelsbach, R. J.; Watt, D. S. J. Org. Chem., 1978, 43, 4758. DOI
Keywords: Enone → Ketal • Ketone → Ketone-α-SeR • Ketal → Ketone • ArylO-H → ArylO-R • ArylO-Me → ArylO-H • ArylO-Me → ArylO-H • Allylic oxidation → Enone • Aldol-Zn → Enone • Selenoxide-Ei → Diene • Ketone → Dienone • ConjReduct-Alkylation • ConjReduct Enone • Ketone enolate+Me-I • Wolff-Kishner • Ketone → CH2 • Mechanism • Enone → Enone-α-SeR • Cu-Me+Enone • Benzene synthesis • Decarboxylation • Robinson annulation, ketoester • Enone enolate+Enone • Mechanism •
Reagents: TsOH • CrO3·Py2 (Collins) • LiNiPr2 • TsOH • LiCuMe2 • LiNiPr2 • H2O2 • HClO4 • Sulfate, dimethyl • Li°/NH3 • MeI • B(Br)3 • Hydrazine • B(Br)3 • SePh-Cl • ZnCl2 • Acetaldehyde • Glycol • HMPA (solvent) • Ethyl vinyl ketone • NaOEt • HCl, EtOH • NaOEt • Ethyl vinyl ketone •

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