| Reference: | Stürmer, R.; Hoffmann, R. W. Chem.Ber. 1994, 127, 2519. DOI |
| Keywords: | CarboxEster -> Alkyl-OH Alkyl-OH -> Aldehyde O-H -> O-PMB Ketal -> Ketone Aldehyde -> CarboxAcid Ozonolysis HWE -> EnoateEster Sharpless epoxidation Epoxide reduction Alkene cleavage Alkene cleavage Lactone-15 Ketal -> Diol B-Allyl+Aldehyde High pressure |
| Reagents: | O3 PPh3 PPh3=C(Me)-CO2R AlH4-Li+ Hydroperoxide, tbutyl Ti(OiPr)4 RuO4-Pr4N+ Alkyl-MgX AlH4-Li+ PMB-Cl OsO4, NMO Periodate, sodium DDQ HCl OsO4, NMO Periodate, sodium CrO3 HCl Benzoyl chloride, 2,4,6-trichloro DMAP |