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Total synthesis of Desoxy-Erythrolaccin:
Reference: Mills, R. J.; Snieckus, V. Tetrahedron Lett. 1984, 25, 479. DOI
Keywords: Alkyl-OH → Ketone • Li/H → Li-Benzyl • Li/H → Li-Aryl • Li/H → Li-Aryl • Lactone-5 • Li-Aryl+Alkyl-X • Alkyl-X+Li-R • Anthraquinone synthesis • Phenol → Quinone • Friedel-Crafts acylation • CarboxAmide → CarboxEster • Si-Alkyl → H-Alkyl •
Reagents: Aryl-Li • BuLi(sec), TMEDA • MeI • Zn° • Acetic anhydride, trifluoro • CrO3 • BuLi(n) • SiMe3-Cl • BuLi(n) • SiMe3-Cl • BuLi(n) • Fluoride, cesium • TsOH •

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