| Reference: | Cesati, III, R. R.; de Armas, J.; Hoveyda, A. H. J. Am. Chem. Soc 2004, 126, 96. DOI |
| Keywords: | Pd-Heck coupling • Ketone -> Enolsilane • Enolsilane -> Ketone enolate • Enyne metathesis • Ketone -> Alkyl-OH • Alkyl-OH -> Ketone • Ketone -> Enolsilane • CarboxAcid -> Alkyl-OH • Vinyl-OTf -> Vinyl-H • Si-Alkynyl -> H-Alkynyl • Olefin cross metathesis • Cu-Me+Enone • ConjAdd(asym) Cu-R • Cu-Me+Enone • ConjAdd(asym) Cu-R • Pd/Sn-Alkynyl+Aryl-X • Stille coupling • Ketone -> Vinyl-OTf • Alkyl-OH -> Alkyl-I • Cu-Vinyl+Alkyl-X • Alkyl-X+Cu-R • Ozonolysis • |
| Reagents: | Methyl vinyl ketone • Pd(OAc)2 • Chiral catalyst • ZnMe2 • Cu(OTf)2 • Alkynyl-SnR3 • Pd(PPh3)4 • BHT • LiTMP • SiMe3-Cl • MeLi • Tf2NPh • HSnBu3 • Pd(PPh3)4 • Carbonate, potassium • Grubbs-Hoveyda • Methyl vinyl ketone • Chiral catalyst • ZnMe2 • Cu(OTf)2 • BH4-Na+ • Li°/NH3 • Dess-Martin • LiNiPr2 • O3 • Me2S • AlH4-Li+ • PPh3, I2 • Vinyl-MgX • CuI • |