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Total synthesis of Epi-Epoxydon:
Reference: Genski, T.; Taylor, R. J. K. Tetrahedron Lett. 2002, 43, 3573. DOI
Keywords: O-SiEt3 → O-H • Morita-Bayliss-Hillman • Enone epoxidation, nucleophilic • CompOx-Enone/Alkene+ROOH • Diels-Alder, Quinone • Bicyclo(221) • O-H → O-SiEt3 • Retro-Diels-Alder → Alkene • Ketone → Alkyl-OH •
Reagents: Quinone • Hydroperoxide, tbutyl • BH4-R4N+ • Formaldehyde • AlEt3 • HF·Py • Cyclopentadiene • Quinone • Epoxide • SiEt3-Cl • Epoxide •

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