| Reference: | Winkler, J. D.; Quinn, K. J.; MacKinnon, C. H.; Hiscock, S. D.; McLaughlin, E. C. Org. Lett. 2003, 5, 1805. DOI |
| Keywords: | Allyl-OH -> Enone • Chelotropic, SO2 • EnoateEster -> Allyl-OH • Allyl-OH -> Enone • Ketone -> Alkyl-OH • O-H -> O-SiMe2tBu • O-SiMe2tBu -> O-H • Diol-1,2 cleavage • Diol -> Carbonate • Epoxidation, V • Epoxide -> Allyl-OH • Grob fragmentation • O-H -> O-Me • Sn-Allenyl+Aldehyde • Aldehyde+Sn-R • Sn-Allenyl+Aldehyde • Enal+Sn-R • Epoxidation, V • Epoxidation, V • Epoxide -> Diol • Furan synthesis • Ketone-α-OR -> Ketone • Diels-Alder, Intram • Ether-5 • Diels-Alder, Allene • |
| Reagents: | Allenyl-SnR3 • SnCl2 • Dess-Martin • AgNO3 • SnCl2 • AlHiBu2 • Permanganate, barium • AlHiBu2 • Hydroperoxide, tbutyl • SiMe2tBu-OTf • Hydroxide, sodium • Periodate, sodium • SmI2 • O=CCl2 • Hydroperoxide, tbutyl - VO(acac)2 • NEt3 • Carbonate, potassium • MeI • VO(acac)2 • Carbonate, calcium • Ag2O • |