| Reference: | Chen, X.-T.; Bhattacharya, S. K.; Zhou, B.; Gutteridge, C. E. Pettus, T. R. R.; Danishefsky, S. J. J. Am. Chem. Soc. J. . 1999, 121, 6563-657. DOI |
| Keywords: | Ketone-α-Halo -> Ketone • Acetal -> Aldehyde • CarboxEster -> Alkyl-OH • O-H -> O-SO2R • Alkyl-OH -> Alkyl-CN • Nitrile -> Aldehyde • O-H -> O-Piv • O-SiMe2tBu -> O-H • Li-Me+Ketone • Enone+Li-R • O-H -> O-SiMe3 • Ketal -> Ketal • O-H -> O-SiMe2tBu • O-C(O)R -> O-H • Alkyl-OH -> Ketone • Ketone -> Vinyl-OTf • O-SiMe2tBu -> O-H • CarboxAcid -> CarboxEster • Ketal -> Diol • Li/Br -> Li-Aryl • Cycloaddition Ketene • Cyclobutane • Retro-Claisen • Li-Aryl+Aldehyde • Furan oxidation • Mechanism • Ether-5 • Pd/Sn-Alkyl+Vinyl-X • Stille coupling • Cr-Vinyl+Aldehyde • Aldehyde+Cr-R • |
| Reagents: | Zn° • Bredereck reagent • TsOH • TsOH • Furyl-Li • AlHiBu2 • DMAP • Cyanide, potassium • 18-cr-6 • AlHiBu2 • Piv-Cl • DMAP • Fluoride, Bu4N+ • Dioxirane • MeLi • SiMe3-OTf • TsOH • AlHiBu2 • RuO4-Pr4N+, NMO • LiN(SiMe3)2 • Pd(PPh3)4 • Chloride, lithium • Fluoride, Bu4N+ • Carbodiimide • TsOH·Py • BuLi(n) • CrCl2 • NiCl2 • |