| Reference: | Madnuson, S. R.; Sepp-Lorenzino, L.; Rosen, N.; Danishefsky, S. J. J. Am. Chem. Soc. 1998, 120, 1615. DOI |
| Keywords: | O-H -> O-SiMe2tBu • Alkyl-OH -> Aldehyde • Pd/Sn-Vinyl+Vinyl-X • Stille coupling • Carbocupration Alkyne • Cu-Vinyl+Alkyne • Alkyne+Cu-R • Singlet oxygen+Diene • Furan+Singlet oxygen • Lactone-5 • Ketone enolate+Alkyl-X • Wolff-Kishner • Aldehyde -> CH2 • Li-Aryl+Aldehyde • Aldehyde+Li-Aryl • Ketone -> Vinyl-OTf • Diels-Alder, Enal • |
| Reagents: | LiCuMe2 • HMPA (solvent) • BHEt3-Li+ • SiPh2tBu-Cl • Tf2O • Vinyl-Sulfide • Montmorillonite • Hydrazine • RuO4-Pr4N+, NMO • Furyl-Li • O2 (singlet) • Iodoacetate • Imidazole • SiMe3-OTf • |