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Total synthesis of Dysidavarone A:
Reference: Schmalzbauer, B.; Herrmann, J.; Muller, R.; Menche, D. Org. Lett. 2013, 15, 964-967. DOI
Keywords: Ketal → Ketone • O-But → O-H • Aryl-H → Aryl-Br • Benzyl-H → Benzyl-Br • Wohl-Ziegler bromination • Birch alkylation • Pd-enolate arylation • Wittig-methyl • Phenol → Quinone • Quinone synthesis • Alkene isomerization • O-H → O-Alkyl (phenol) • O-H → O-Alkyl (phenol) •
Reagents: Sulfate, diethyl • NBS • TfOH • NBS • AIBN • Pd(OAc)2 • Li°/NH3 • HCl, H2O • HCl • O2 • Salcomine • PPh3=CH2 • KOtBu • Salcomine •

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