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Total synthesis of Male Dried Bean Beetle Sex Pheromone:
Reference: Kocienski, P.; Cernogliaro, G.; Feldstein, G. J. Org. Chem. 1977, 42, 353. DOI
Keywords: Claisen-Johnson - Propargyl-OH • CarboxEster → Alkyl-OH • Fischer esterification • CarboxEster → CarboxEster-α-SeR • Selenoxide-Ei → EnoateEster • CarboxEster → EnoateEster • Mg-Alkyl+CO2 • Alkyl-OH → Alkyl-Br •
Reagents: Orthoacetate • AlHiBu2 • PPh3, CBr4 • Alkyl-MgX • Alkyl-MgX • CO2 • LiNiPr2 • Diselenide, phenyl • Periodate, sodium • AlH4-Li+

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