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Total synthesis of Disparlure:
Reference: Li, L. H.; Wang, D.; Chan, T. H. Tetrahedron Lett. 1997, 38, 101. DOI
Keywords: Sharpless epoxidation • Carbocupration Alkyne • Cu-Alkyl+Alkyne • Cu-Vinyl+Alkyl-X • Alkyl-X+Cu-R • Si-Oxiranyl → H-Oxiranyl •
Reagents: Alkyl-MgX • CuI • P(OMe)3 • Vinyl-Cu • NiBr • DIPT • Hydroperoxide, tbutyl • Fluoride, R4N+

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