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Total synthesis of Dievodiamine:
Reference: Unsworth, W. P.; Kitsiou, C.; Taylor, R. J. Org. Lett. 2013, 15, 3302-3305 DOI
Keywords: Curtius • C-CO2H → C-N • Mg-Alkynyl+Iminium • Iminium+Mg-R • Alkyne Hydrostannation • Stille coupling • Pd/Sn-Vinyl+Aryl-X • Friedel-Crafts Acylation • CarboxAmide → Amidine • Amidine synthesis • Aryl-H → Aryl-I • CarboxAcid → CarboxCl • CarboxCl → CarboxAmide • Amidine synthesis • CarboxAmide → Amidine • Lactam-6 •
Reagents: Azide, diphenylphosphoryl • NEt3 • BF3·OEt2 • POCl3 • Alkynyl-MgX • Chloride, lithium • HSnBu3 • AIBN • Oxalyl chloride • Hydroxide, potassium • NIS • PdCl2(PPh3)2 • CuI •

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