| Reference: | McFadden, R. M.; Stoltz, B. M. J. Am. Chem. Soc. 2006, 128, 7738 DOI |
| Keywords: | Chiral catalyst • Wacker oxidation • Alkene -> Ketone • Aldol-K -> Enone • Robinson annulation, ketone • Aldol-K -> Enone • Enone enolate+Enone • ConjAdd Enolate • Enone -> Vinyl-OTf • Pd/Mg-Vinyl+Aryl-OTf • Kumada coupling • Friedel-Crafts Acylation • Baeyer-Villiger -> Phenol • Phenol -> Quinone • Pd-Enolate allylation(asym) • Tsuji-Trost allylation • Ketone enolate+Chlorocarbonate • |
| Reagents: | LiN(SiMe3)2 • O=C(OAllyl)Cl • Pd2(dba)3 • PHOX • PdCl2 • Cu(OAc)2 • O2 • Hydroxide, potassium • LiN(SiMe3)2 • Methyl vinyl ketone • Hydroxide, potassium • LiNiPr2 • Tf2NPh • Propenyl-MgX • Pd(PPh3)4 • HCl • Cl2CH-OMe • TiCl4 • H2O2 • H2SO4 • IBX • HS-C6F5 • O2 • Hydroxide, sodium • Chiral catalyst • |