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Total synthesis of Dendrobatid Toxin:
Reference: Overman, L. E.; Bell, K. L. J. Am. Chem. Soc. 1981, 103, 1851. DOI
Keywords: Hydroalumination Alkyne • Al-Vinyl+Epoxide • Epoxide+Al-R • Si-Vinyl+Iminium • Iminium+Si-R • Amine-6 •
Reagents: AlHiBu2 • MeLi • Vinyl-Al • Epoxide • Hydroxide, potassium • Formaldehyde • Camphor sulfonic acid •

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