| Reference: | Reich, H. J.; Eisenhart, E. K.; Olson, R. E.; Kelly, M. J. J. Am. Chem. Soc. 1986, 108, 7791. DOI |
| Keywords: | Enolsilane -> Ketone enolate • Enolsilane -> Ketone-α-SeR • Selenoxide-Ei -> Enone-6 • Ketone -> Enone • Nozaki-Takai -> Ene • Ketone -> C=CH2 • Brook elimination • Silyl ketone Brook • Li-Sulfone+Ketone • Brook elimination • Silyl ketone Brook • Diels-Alder, Intram • Hydrogenation Alkene • Diimide+Alkene • CompRed-Alkene/Enone+Diimide • Mechanism • CompE+-EnolSi/EnolSi+Li-R • Li/I -> Li-Vinyl • |
| Reagents: | MeLi • AlEt2-Cl • CH2Br2, Zn°, TiCl4 • SePh-Cl • Perbenzoic acid, 3-chloro • NHEt2 • Diimide • Hydrazine • Rh(PPh3)3Cl • LiCHR-Sulfonyl • LiNiPr2 • Silyl ketone • Vinyl-Li • BuLi(n) • Silyl ketone • |