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Total synthesis of Davanone, (+):
Reference: Morrison, K. C.; Litz, J. P.; Scherpelz, K. P.; Dossa, P. D.; Vosburg, D. A. Org. Let. 2009, 11, 2217. DOI
Keywords: CarboxEster -> CarboxAmide(Weinreb) • CarboxAmide(Weinreb)+Mg-R • Mg-Alkyl+CarboxAmide(Weinreb) • Allylic oxidation -> Allyl-OH • CompOx-Alkene/Alkene+SeO2 • Sharpless epoxidation • Bode epoxide elimination • Pd-allyl-O coupling • Ether-5 •
Reagents: SeO2 • Hydroperoxide, tbutyl • DMSO, Py·SO3 • Thiazolium • Chiral catalyst • TunePhos • HCl • Alkyl-MgX •

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