| Reference: | Hauser, F. M.; Mal, D. J. Am. Chem. Soc., 1983, 105, 5688. DOI |
| Keywords: | Diels-Alder, EnoateEster CarboxEster -> Alkyl-OH Alkene cleavage CarboxAcid -> CarboxCl O-C(O)R -> O-H Alkyl-OH -> Aldehyde Nitrile -> CarboxAcid Alkyl-X -> Alkyl-CN Cu-Me+CarboxCl CarboxCl+Cu-R Aldol-H+ -> Enone Anthraquinone synthesis ConjAdd Li-R Mechanism |
| Reagents: | AlH4-Li+ MeSO2Cl Cyanide, sodium Hydroxide, potassium RuO4 Periodate, sodium SOCl2 LiCuMe2 Hydroxide, sodium CrO3·Py2 (Collins) HCl, THF DMF (solvent) O2 Hydroquinone Acrylate Cyclohexadiene DMF (solvent) LiOtBu |