| Reference: | Williams, D. R.; Patnaik, S.; Clark, M. P. J. Org. Chem. 2001, 66, 8463. DOI |
| Keywords: | CarboxEster -> Aldehyde EnoateEster -> Allyl-OH CarboxAmide(Evans) -> CarboxEster O-H -> O-Me Alkyl-OH -> Aldehyde CarboxEster -> Alkyl-OH Alkyl-OH -> KetoEster CarboxEster enolate+Aldehyde Thiazole synthesis Mechanism HWE -> EnoateEster Allyl-OH -> Enal Ketone -> Enolether Aldol-B-Evans Chiral auxiliary |
| Reagents: | AlHiBu2 P(O)(OR)2CH2-CO2R NaH AlHiBu2 MeMgBr MeI Dess-Martin AlHiBu2 CH2=C(OLi)(OR) LiNiPr2 Dess-Martin Me2SO4 SiiPr3-OTf Bromopyruvate DMSO, (COCl)2 DMSO (solvent) NaH HMPA (solvent) |