| Reference: | Smith, A. B.; Kozmin, S. A.; Paone, D. V J. Am. Chem. Soc. 1999, 121, 7423. DOI |
| Keywords: | CarboxAmide(Evans) -> CarboxEster • Williamson esterification • CarboxEster -> Alkyl-OH • O-H -> O-MOM • O-Bn -> O-H • Li/I -> Li-Alkyl • Alkene cleavage • Li-Dibromomethyl+Ketone • Kowalski reaction • Li-Dibromomethyl+CarboxEster • Kowalski reaction • O-MOM -> O-H • Alkyl-OH -> Aldehyde • Aryl-OMe -> Aryl-OH • Danheiser benzannulation • CarboxAmide enolate(Evans)+Alkyl-X • Li-Alkyl+Ketone • Enone-β-OR+Li-R • Stork-Danheiser • Wittig-methyl • RCM -> Ring-C • Ynol-OSi • Aryl-OH -> Aryl-OR • Benzene synthesis • Lemieux-Johnson oxidation • Alkyl-OH -> Alkyl-I • Hydrogenation Alkene • Li/I -> Li-Alkyl • Mechanism • Hydrazone+Li-Alkyl • |
| Reagents: | NaN(SiMe3)2 • H2O2, LiOH • Carbonate, potassium • CH2Br2, LiTMP • BuLi(n) • CH2Br2, LiTMP • BuLi(n) • AlH4-Li+ • Cl-CH2-OR • H2, Pd • PPh3, I2 • Alkyl-Li • BuLi(tert) • Fluoride, Bu4N+ • Carbonate, potassium • HCl • PPh3, I2 • OsO4, NaIO4 • Hydrazine, tosyl • HCl, MeOH • Dess-Martin • PPh3=CH2 • H2, Pd • BBr3 • Allyl-Br • Grubbs I • SiiPr3-OTf • SiMe2tBu-OTf • Imidazole • BuLi(tert) • |