| Reference: | Li, C.; Pace, E. A.; Liang, M.-C.; Lobkovsky, E.; Gilmore, T. D. Porco, J. A. J. Am Chem. Soc. 2001, 123, 11308. DOI |
| Keywords: | Enone -> Ketal Pd/Sn-Vinyl+Vinyl-X Stille coupling Enone -> Allyl-OH Ketal -> Enone Epoxidation, nucleophilic(asym) Enone Phenol -> Quinone Epoxidation, peracid Henbest O-SiPh2tBu -> O-H Epoxide -> Diol Ether-6 |
| Reagents: | Iodosobenzene-OAc Hydroperoxide, trityl DEET Vinyl-SnR3 Pd2(dba)3 AlHiBu2 Perbenzoic acid, 3-chloro HF Acetonitrile (solvent) HF Acetonitrile (solvent) |