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Total synthesis of Cycloepoxydon:
Reference: Li, C.; Pace, E. A.; Liang, M.-C.; Lobkovsky, E.; Gilmore, T. D. Porco, J. A. J. Am Chem. Soc. 2001, 123, 11308. DOI
Keywords: Enone -> Ketal • Pd/Sn-Vinyl+Vinyl-X • Stille coupling • Enone -> Allyl-OH • Ketal -> Enone • Epoxidation, nucleophilic(asym) Enone • Phenol -> Quinone • Epoxidation, peracid • Henbest • O-SiPh2tBu -> O-H • Epoxide -> Diol • Ether-6 •
Reagents: Iodosobenzene-OAc • Hydroperoxide, trityl • DEET • Vinyl-SnR3 • Pd2(dba)3 • AlHiBu2 • Perbenzoic acid, 3-chloro • HF • Acetonitrile (solvent) • HF • Acetonitrile (solvent) •

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