| Reference: | Whitlock, H. W.; Smith, G. L. J. Am. Chem. Soc., 1967, 89, 3600 DOI |
| Keywords: | Enone -> Allyl-OH • Pictet-Spengler • Li-Nitrile+CarboxEster • CarboxEster+Li-Nitrile • Nitrile -> CarboxEster • Decarboxylation • Claisen acylation, ester • Ketone enolate+CarboxEster • Aziridine • Imine -> Amine • Ketone -> Ketone-α-Halo • Dehydrohalogenation -> Enone • Allyl-OH isomerization • 1,3-Sigmatropic • Amine-5 • |
| Reagents: | NaOEt • HCl, MeOH • Acetic acid • NaOMe • Aziridine • H2, Pt • Bromine • Acetic acid • Chloride, lithium • DMF (solvent) • AlH4-Li+ • BuLi(n) • TsCl • Iodide, sodium • |