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Total synthesis of Conduritol B, F:
Reference: Heo, J. N.; Holson, E. B.; Roush, W. R. Org. Lett. 2003, 5, 1697-1700. DOI
Keywords: Alkene → Diol-1,2 • O-Bn → O-H • O-Bn → O-H • O-Bn → O-H • RCM → Ring-C • Peterson → Ene • Si-Alkyl → HO-Alkyl • Peterson → Ene • B-Allyl-Ipc+Aldehyde • Aldol-B-Ipc •
Reagents: OsO4, NMO • KN(SiMe3)2 • 18-cr-6 • H2SO4 • Hg(OAc)2 • Peracetic acid • Na°/NH3 • Na°/NH3 • Na°/NH3 • Grubbs II • Allyl-B(Ipc)2 • Chiral auxiliary-Boronate •

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