| Reference: | Parker, K. A.; Fokas, D. J. Am. Chem. Soc. 1992, 114, 9688. DOI; J. Org. Chem. 2006, 71, 449. DOI |
| Keywords: | N-H -> N-SO2R • Luche reduction • Enone -> Allyl-OH • N-H -> N-Me • Epoxide -> Allyl-OH • O-H -> O-SiMe2tBu • Mitsunobu -> Ether • Alkyl-OH -> Alkyl-OR • Alkyl-OH -> Ketone-α-OR • ConjAdd Amine • Amine-6 • Birch reduction • Epoxidation, peracid • Henbest • Ether-5 • HWE -> EneSulfide • O-SiMe2tBu -> O-H • Radical cyclization(Aminyl) • Amine-6 • Radical cyclization(Aryl) • |
| Reagents: | Li°/NH3 • TsCl, NEt3 • BH4-Na+, CeCl3 • Carbonate, potassium • Perbenzoic acid, 3-chloro • Ti(OiPr)4 • SiMe2tBu-OTf • PBu3, DEAD • Li°/NH3 • DMSO, (COCl)2 • HSnBu3 • AIBN • P(O)(OR)2CH2-SR • BuLi(n) • HF • NEt3 • |