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Total synthesis of Clovene:
Reference: Schultz, A. G.; Dittani, J. P. J. Org. Chem., 1983, 48, 2318. DOI
Keywords: Enone enolate+Alkyl-X • Alkyl-X+Enolate • Cyclohexane • Enone enolate+Alkyl-X • Alkyl-X+Enolate • Enone enolate+Alkyl-X • Alkyl-X+Enolate • Enone enolate+Alkyl-X • Deconjugative alkylation • Alkyl-X+Enolate • Aldol-K → Enone • Cyclopentanone • Enone enolate+Alkyl-X • Alkyl-X+Enolate • Enone-β-OR → Enone • Enone-β-OR+Al-H • Stork-Danheiser • ConjReduct Enone • Enol → EnAmine • Claisen acylation, formate • Jones oxidation • Acetate pyrolysis • Ozonolysis • Ketone → Alkyl-OH • Enone enolate+Alkyl-X •
Reagents: LiNiPr2 • MeI • LiNiPr2 • AlH4-Li+ • HCl, H2O • LiNiPr2 • Allyl-Br • LiNiPr2, HMPA • BH(sBu3)-K+ • O3 • Hydroxide, potassium • Li°/NH3 • KOtBu • O=C(OR)Cl • AlH4-Li+ • Hydroxide, potassium • NaNH2 • Formate, ethyl • CrO3, H2SO4 (Jones) • Me2S • HMPA (solvent) •

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