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Total synthesis of Clavilactone B:
Reference: Larrosa, I.; DaSilva, M. I.; Gomez, P. M.; Hannen, P.; Ko, E.; Lenger, S. R.; Linke, S. R.; White, A. J. P.; Wilton, D.; Barrett, A. G. M. J. Am. Chem. Soc. 2006, 128, 14042. DOI
Keywords: O-SiMe2tBu → O-H • Alkyl-OH → CarboxAcid • Lactone-5 • Li/H → Li-Aryl • Benzyne • Mg-Aryl+Aldehyde • Aldehyde+Mg-R • Felkin-Anh • RCM → Lactone • Quinone synthesis •
Reagents: BuLi(n) • Allyl-MgX • Fluoride, R4N+ • Iodosobenzene-OAc • Grubbs II • Quinone • Ceric ammonium nitrate •

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