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Total synthesis of Citreoviral:
Reference: Williams, D. R.; White, F. H. J. Org. Chem. 1987, 52, 5067 DOI
Keywords: O-H → O-MEM • Ozonolysis • Ozonolysis • O-MEM → O-H • O-C(O)R → O-H • EnoateEster → Allyl-OH • Allyl-OH → Enal • Mg-Vinyl+Ketone • Mg-Vinyl+Aldehyde • Felkin-Anh • Dehydrohalogenation → Allyl-OR • Wittig-carboxymethyl → EnoateEster • Felkin-Anh Chelation • O-H → O-Bn • Iodoetherification • Ether-5 •
Reagents: Vinyl-MgX • MEM-Cl • Vinyl-MgX • DBU • O3 • PPh3=C(Me)-CO2R • ZnBr2 • AlHiBu2 • MnO2 • I2, NaHCO3 • Benzoyl chloride •

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