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Total synthesis of Chorismic Acid Analog:
Reference: Mattia, K. M.; Ganem, B. J. Org. Chem. 1994, 59, 720. DOI
Keywords: O-H → O-SiMe2tBu • Claisen-Enol ether • HWE → EnoateEster • Epoxide+Selenolate • Furst-Plattner diaxial • Epoxidation, peracid • Dehydrohalogenation → Enoate • Selenoxide-Ei → Allyl-OR •
Reagents: SiMe2tBu-Cl • SeMe-AlMe2 • NaOMe • Epoxide • Selenol, phenyl • BF3·OEt2 • Peracetic acid, trifluoro • Rh2(OAc)4 • LiNiPr2 • Formaldehyde • Selenolate, phenyl • Diazophosphonate • Imidazole • Dioxirane •

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