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Total synthesis of Cerulenin:
Reference: Corey, E. J.; Williams, D. R. Tetrahedron Lett., 1977, 3847. DOI
Keywords: Li/Sn → Li-Vinyl • O-THP → O-H • Li/I → Li-Alkyl • CarboxAcid → CarboxEster • CarboxEster → CarboxAmide • Li/Sn → Li-Vinyl • Li-Vinyl+Alkyl-X • Alkyl-X+Li-R • Li/I → Li-Alkyl • Hydrostannation Alkyne • Li-Alkyl+CarboxAnhydride • Finkelstein reaction • Alkyl-OH → Alkyl-I • Finkelstein reaction •
Reagents: Vinyl-SnR3 • Alkyl-Li • HSnBu3 • AIBN • BuLi(n) • Acetic acid • BuLi(tert) • Diazomethane • NH3 • Sulfonyl chloride, methane, NEt3 • Iodide, sodium • Allyl-Br •

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