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Total synthesis of Cecropia Juvenile Hormone:
Reference: Faulkner, D. J.; Peterson, M. R. J. Am. Chem. Soc. 1973, 95, 553. DOI
Keywords: Enone → Allyl-OH • Enone → Ketal(Me) • Mannich • Ketone → Alkyl-OH • O-H → O-SO2R • Claisen-Enol ether • Aldehyde → Cyanohydrin • Nitrile → CarboxEster • Hofmann elim → Enone • Diol-1,2 → Epoxide • CompRed-Ketone/CarboxEster+B-H • CompRed-Ketone/CarboxEster+B-H • Alkyne hydration • Claisen-Enol ether •
Reagents: BH4-Na+ • Cyanide, sodium • Acetic acid • Orthoformate • TsOH • Formaldehyde • CH2=NMe2+I- • Sulfate, dimethyl • Hydroxide, sodium • TsOH • BH4-Na+ • TsCl, Py • NaOMe • Alkynyl-Li • HgO • Methacrolein • TsOH •

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