image

Total synthesis of Cecropia Juvenile Hormone:
Reference: Still, W. C.; McDonald, J. H.; Collum, D. B.; Mitra, A. Tetrahedron Lett. 1979, 593. DOI
Keywords: O-H -> O-SO2R • O-Ethoxyethyl -> O-H • Li-Vinyl+Aldehyde • Li-Vinyl+Aldehyde • O-H -> O-Alkyl • Alkyl-OSO2R -> Alkyl-H • Li/Sn -> Li-Ether • 2,3-Sigmatropic Anionic •
Reagents: Vinyl-Li • BuLi(tert) • KH • SnBu3-CH2-I • TsCl, Py • Acetic acid • BuLi(n) •

Syntheses Home