| Reference: | Curran, D. P.; Ko, S. B.; Josien, H. Angew. Chem., Int. Ed. Engl. 1996, 34, 2683. DOI |
| Keywords: | Alkene -> Diol-1,2 • Lactam-6 • Pd-Heck coupling • Li/H -> Li-Pyridyl • Li-Aryl+CarboxAmide • CarboxAmide+Li-R • Sharpless dihydroxylation • Alkene -> Diol-1,2(asym) • Lactone-6 • Si-Aryl -> Aryl-I • N-H -> N-Propargyl • Reductive etherification • Radical cyclization(Vinyl) • Quinoline synthesis • Isocycanide radical • Mechanism • |
| Reagents: | BuLi(tert) • DMF (react) • BuLi(n) • I2 • HSiEt3 • Acetic acid, trifluoro • Pd(OAc)2 • Carbonate, potassium • Bromide, Bu4N+ • OsO4 • Pyridine • Carbonate, calcium • I2 • SiMe3-I • Bromide, lithium • DMF (solvent) • Propargyl-Br • Pyridyl-Li • Isocyanide • SnMe3-SnMe3 • Photochemistry • |