| Reference: | Coates, R. M.; Shaw, J. E. J. J. Am. Chem. Soc. 1970, 92, 5657 DOI |
| Keywords: | Dehydration -> Enone • Ketone -> Enamine • Robinson annulation, Enamine • Enamine ConjAdd • Enone -> Ketal(thio) • Ketal(thio) -> CH2 • Claisen acylation, carbonate • Ketone enolate+Carbonate • CompE+-CarboxEster/Ketone+Li-R • Li-Me+Ketoester • Pyrazoline • Cyclopropane • Azo fragmentation • |
| Reagents: | Pyrrolidine • Methyl vinyl ketone • Acetate, sodium • Acetic acid • TsOH • H2, RaNi • NaH • O=C(OR)2 • MeLi • HCl • Hydrazine • Hydroxide, potassium • |