| Reference: | Ratcliffe, R.; Heathcock, C. H. J. Am. Chem. Soc. 1971, 93, 1746. DOI |
| Keywords: | O-H -> O-C(O)R • Ketone -> Ketal • O-C(O)R -> O-H • O-H -> O-Bn • Alkyl-OH -> Ketone • Hydroboration Alkene • Alkyl-OH -> Ketone • O-Bn -> O-H • O-H -> O-SO2R • Hydroboration Alkene • Ketone epimerization • Wittig-alkyl+Ketone • Wittig-methyl • Hydrogenation Alkene • CompRed-Alkene/Ketone+H2 • Ketone epimerization • Li-Me+Ketone • Wagner-Meerwein • Wagner-Meerwein • |
| Reagents: | Acetic anhydride, Py • Glycol • AlH4-Li+ • NaH • BH3 • H2O2, NaOH • CrO3·Py2 (Collins) • NaOMe • PPh3=CH2 • Acetic acid • Al2O3 • PPh3=CH-Me • BH3 • H2O2, NaOH • CrO3·Py2 (Collins) • H2, Pd • TsCl, Py • H2, Pd • TsCl, Py • Acetic acid • MeLi • Wieland-Miescher • Acetic acid • |