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Total synthesis of Brevicomin, exo:
Reference: Matteson, D. S.; Sadhu, K. M. J. Am. Chem. Soc. 1983, 105, 2077. DOI
Keywords: Li-Dichloromethyl+Borane • Ketal → Ketone • O-Bn → O-H • Li-Dichloromethyl+Borane • Mg-Alkyl+Borane • Borane+Mg-R • Metalate rearrangement (B) • Metalate rearrangement (B) • B-Alkyl → HO-Alkyl •
Reagents: LiCHCl2 • ZnCl2 • LiOCH2Ph • LiCHCl2 • ZnCl2 • H2O2, NaOH • H2, Pd • Alkyl-MgBr • Chiral auxiliary-Boronate •

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