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Total synthesis of Bourbonene:
Reference: White, J. D.; Gupta, D. N. J. J. Am. Chem. Soc. 1966, 88, 5364-5365. DOI
Keywords: Allyl-OH → Allyl-Cl • Ketone azaenolate+Alkyl-X • Alkyl-X+Azaenolate • Ketone → Imine • Claisen acylation, formate • Ketone enolate+Formate • KetoAldehyde → Allyl-OH • Allyl-X → Allyl-H • Photochemistry 2+2 • Wittig-methyl • Alkene isomerization •
Reagents: Alkyl-MgBr • NaOMe • Formate, ethyl • AlH4-Li+ • SOCl2 • AlH4-Li+ • Photochemistry • PPh3=CH2 • HCl, EtOH •

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