| Reference: | Corey, E. J.; Seibel, W. L. Tetrahedron Lett., 1986, 27, 905. |
| Keywords: | O-SiMe2tBu -> O-H --- Cu-Vinyl+Me-I --- Metalate rearrangement (B) --- B-Alkynyl+Me3Si-OTf --- B-Vinyl -> Cu-Vinyl --- Si-Vinyl+Allyl-X --- Li-Alkynyl+Borane |
| Reagents: | Alkynyl-BR2 --- Alkynyl-BR2 --- SiMe3-OTf --- Vinyl-B --- BuLi(n) --- CuI --- Vinyl-Cu --- MeI --- Fluoride, Bu4N+ --- TiCl4 --- NHMePh --- Vinyl-SiR3 --- HMPA (solvent) |