image

Total synthesis of Aspidospermine:
Reference: Benchekroun-Mournir, N.; Dugat, D.; Gramain, J. C. Tetrahedron Lett. 1992, 33, 4001. DOI
Keywords: Photochemistry • Amine-5 • Amine-5 • Enone enolate+Alkyl-X • Alkyl-X+Enolate • Ketone enolate+Vinyl-NO2 • Vinyl-NO2+Enolate • Ketone → Enamine • Reductive amination, H2 • Nitro → Amine •
Reagents: LiNiPr2 • LiNiPr2 • Photochemistry • LiNiPr2 • Vinyl-NO2 • H2, Pt • Al2O3 • Photochemistry •

Syntheses Home