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Total synthesis of Aspidospermine:
Reference: Benchekroun-Mournir, N.; Dugat, D.; Gramain, J. C. Tetrahedron Lett. 1992, 33, 4001. DOI
Keywords: Photochemistry • Amine-5 • Amine-5 • Enone enolate+Alkyl-X • Alkyl-X+Enolate • Ketone enolate+EneNitro • EneNitro+Enolate • ConjAdd Li-R • Ketone → EnAmine • Reductive amination, H2 • Amine-5 • Amine-6 • Nitro → Amine • Iminium → Amine •
Reagents: LiNiPr2 • LiNiPr2 • Photochemistry • LiNiPr2 • EneNitro • H2, Pt • Al2O3 • Photochemistry • Pd/C •

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