| Reference: | Sharp, L. A.; Zard, S. Z. Org. Lett. 2006, 8, 831-834. DOI |
| Keywords: | Aryl-OH -> Aryl-OR • Friedel-Crafts Acylation • Lactone-5 • Birch alkylation • Fischer Indole • Indole synthesis • Hydrogenolysis Ketone • Ketone -> CH2 • CarboxAmide -> Amine • CompRed-CarboxAmide/Ketone+B-H • CompRed-CarboxAmide/CarboxEster+B-H • CarboxEster enolate+Alkyl-X • Bromoacetate+Enolate • Decarboxylation Krapcho • Lactam-5 • Mechanism • Radical cyclization(Aminyl) • |
| Reagents: | Acetyl chloride • H2, Pd • Carbonate, potassium • Li°/NH3 • HCl, H2O • O=C(OR)Cl • Benzoyl chloride • BH-BBN • Chloride, lithium • Hydrazine, phenyl • BH4-Na+ • Bromoacetate • DMF (solvent) • HSnBu3 • |