| Reference: | Zu,L.; Boal, B. W.; Garg, N. K. J. Am. Chem. Soc. 2011, 133, 8877–8179. DOI |
| Keywords: | Ketone -> Ketal(Me) N-Bn -> N-H N-H -> N-SO2R Ketal -> Ketone Ketone -> Alkyl-OH Alkyl-OH -> Ketone N-SO2R -> N-H Fischer indole Diels-Alder, Maleic anhydride Decarboxylation Oxidative N-H -> N-SO2R Pd-Heck coupling Enone -> Ketone Ketone enolate+Alkyl-X Alkene cleavage Lactone-6 Lactone -> Ester Ether-5 Ketone -> Hydrazone |
| Reagents: | Orthoformate TsOH Na°/NH3 BuLi(n) Carbonate, potassium Pd(PPh3)4 Piperidine, pentamethyl FeCl3 In° LiN(SiMe3)2 Allyl-I DMPU (solvent) BH4-Na+ OsO4, NaIO4 BH4-Na+ H2SO4 Dess-Martin Hydrazine, phenyl Carbonate, potassium Mg° Formic acid |