| Reference: | Hu, T.; Corey, E. J. Org. Lett. 2002, 4, 2441. DOI |
| Keywords: | Ketone enolate+Alkyl-X • Alkyl-X -> Alkyl-SO2R • Pd-Enolate allylation • Tsuji-Trost allylation • McMurry coupling -> Ene • CompE+-Allyl-Br/Carbonate+Enolate • Tsuji-Trost allylation • Pd-Enolate allylation • Ozonolysis • CompOx-Alkene/Alkene+O3 • Ketone -> Ketone-α-Halo • Ketone-α-S(O)nR -> Ketone • Silyl ketone Brook • Mechanism • |
| Reagents: | TASF • SiMe3-OTf • Sulfinate, benzene • Pd(PPh3)4 • Al(Hg) • O3 • Zn/Cu • SiMe3-OTf • NEtiPr2 • Carbonate, calcium • Pd2(dba)3 • Me2S • Acetate, potassium • Silyl ketone • Propenyl-Li • Allyl-Br • |