| Reference: | Corey, E. J.; Kang, J. Tetrahedron Lett., 1982, 23, 1651. DOI |
| Keywords: | Cu-Vinyl+Allenyl-I • Allenyl-X+Cu-R • Li/Sn -> Li-Vinyl • Hydroboration Alkyne • Alkyne -> Ene-cis • Li-Alkynyl+Alkyl-X • Li/H -> Li-Alkynyl • Li/I -> Li-Vinyl • Hydrostannation Alkyne • Si-Propargyl -> Allenyl-I • Sn-Vinyl -> Vinyl-I • Cu-Vinyl+Allenyl-I • Allenyl-X+Cu-R • |
| Reagents: | BuLi(n) • I2 • BH(Siam)2 • Acetic acid • BuLi(tert) • CuI·SMe2 • Alkynyl-Li • I2 • AgOAc • SiMe3-CH2Cl • HMPA (solvent) • HSnBu2H • Vinyl-SnR3 • Vinyl-Li • CuI·SMe2 • |