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Total synthesis of Aflatoxin-M1 New:
Reference: Buchi, G.; Weinreb, S. J. Am. Chem. Soc. 1969, 91, 5408-5409. DOI
Keywords: Aryl-OH -> Aryl-OR • Aryl-OMe -> Aryl-OH • Aryl-OBn -> Aryl-OH • Ketone-α-Halo -> Ketone-α-OR • Ketone+Mg-Allyl • Alkene cleavage • Lemieux-Johnson oxidation • Aldehyde -> Acetal • Acetate pyrolysis •
Reagents: Me2SO4 • Carbonate, potassium • AlCl3 • Carbonate, potassium • Carbonate, calcium • Allyl-MgX • OsO4, NaIO4 • H2, Pd • Acetic anhydride • Flash vacuum pyrolysis • Bicarbonate, sodium • ZnCO3

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