| Reference: | Munchhof, M. J.; Heathcock, C. H. J. Org. Chem. 1994, 59, 7566. DOI |
| Keywords: | CarboxAmide(Evans) -> CarboxEster CarboxEster -> Alkyl-OH O-H -> O-CPh3 Luche reduction Enone -> Allyl-OH O-H -> O-SiMe2tBu Alkyl-OH -> Aldehyde Alkyl-OH -> Ketone O-THP -> O-H O-SiMe2tBu -> O-H CarboxAmide(Weinreb)+Li-R Li-Vinyl+CarboxAmide Aldol-B-Evans 2,3-Sigmatropic Sulfoxide Lactone enolate+Aldehyde Aldol-Li -> Aldol Lactone-6 CarboxAcid -> CarboxAmide(Weinreb) CarboxAmide(Evans) -> CarboxEster Claisen-Ireland |
| Reagents: | LiOCH2Ph AlHiBu2 Ph3CCl O=C(Im)2 Vinyl-Li BH4-Na+, CeCl3 Perbenzoic acid, 3-chloro P(OMe)3 SiMe2tBu-OTf ZnBr2 DMSO, Py·SO3 Dess-Martin Acetic acid BHsBu3-Li+ Diazomethane HF·Py DMAP NMe(OMe)-H LiNiPr2, HMPA SiMe2tBu-Cl |