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Total synthesis of Acoradiene:
Reference: Ficini, J.; Revial, G.; Genet, J. P. Tetrahedron Lett. 1981, 22, 629, 633. DOI
Keywords: Ketone → EnolEther • O-H → O-P(O)(OR)2 • Wittig-methyl → Diene • Enamine → Ketone • Allyl-OR → Allyl-H • Ynamine+CarboxEster • Mechanism •
Reagents: PPh3=CH2 • TsOH • Acetic acid • MeLi • P(O)(OR)2Cl • Li°/NH3 • Ynamine •

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