| Reference: | Bachmann, W. E.; Cole, W.; Wilds, A. L. J. Am. Chem. Soc. 1939, 61, 974-975. DOI |
| Keywords: | CarboxEster -> CarboxAcid • CompE+-CarboxEster/CarboxEster+KOH • EnoateEster -> CarboxEster • CarboxAcid -> CarboxEster • Claisen acylation, oxalate • Ketone enolate+CarboxEster • Decarbonylation • Acetoacetic ester synthesis • Dehydration -> Enoate • Diazoketone • Arndt-Eistert • Dieckmann • CarboxEster enolate+CarboxEster • Decarboxylation • Reformatsky • CarboxEster enolate+Ketone • Steroid synthesis • |
| Reagents: | Oxalate • MeI • NaOMe • Bromoacetate • SOCl2 • Hydroxide, potassium • Na(Hg) • Diazomethane • Hydroxide, sodium • SOCl2 • Diazomethane • Ag2O • NaOMe • HCl • NaOMe • |