| Reference: | Trost, B. M.; Curran, D. P. J. Am. Chem. Soc. 1981, 103, 7380 |
| Keywords: | Si-Allyl+Fluoride+Ketone --- Sakurai allylation --- Ketone -> Ketal --- Sulfide -> Sulfone --- Cyclopropane Hydrogenolysis --- Dehydration -> Ene --- Epoxidation, peracid --- Ketal -> Ketone --- Dehydrosulfonylation -> Enone --- Epoxidation, peracid --- Ketone -> Enolsilane --- Epoxide reduction --- O-H -> O-SiMe3 --- Mannich --- O-SiMe3 -> O-H --- ConjAdd M-SR --- Ketone -> Ketone-α-SR --- Ketone enolate+Allyl-X --- Simmons-Smith --- Dienone -> Enone --- Epoxide -> Allyl-OH --- Hoffmann elim -> Enone |
| Reagents: | Allyl-SiR3 --- Fluoride, Bu4N+ --- NEt3 --- Glycol --- Camphor sulfonic acid --- Disulfide, methyl --- KH --- Allyl-SiR3 --- Allyl-SiR3 --- KH --- Perbenzoic acid, 3-chloro --- CH2I2, ZnEt2 --- H2, Pt --- SOCl2 --- Perbenzoic acid, 3-chloro --- HClO4 --- DBU --- Li°/NH3 --- Perbenzoic acid, 3-chloro --- DBU --- LiNiPr2, HMPA --- SiMe3-Cl --- Na°/Naphth --- CH2=NMe2+I- --- HF·Py --- MeI --- DBU |