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Total synthesis of Coleophomone D:
Reference: Nicolaou, K. C.; Montagnon, T.; Vassilikogiannakis, G.; Mathison, C. J. N. J. Am. Chem. Soc. 2005, 127, 8872. DOI
Keywords: Cyanohydrin -> AcylCyanide --- Benzyl-OH -> Aldehyde --- Selenoxide-Ei -> Dienone-6 --- Ketone -> Enone --- Enone enolate+Allyl-X --- Claisen acylation, Mander --- Enone enolate+Mander --- Cyanohydrin
Reagents: LiNiPr2 --- LiNiPr2 --- LiNiPr2 --- H2O2 --- Hydroxide, lithium --- AlEt2-CN --- CrO3Cl·PyH (PCC) --- NEt3 --- Carbonate, potassium --- MnO2 --- SePh-Cl --- Allyl-Br

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