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Total synthesis of Chorismic Acid Analog:
Reference: Mattia, K. M.; Ganem, B. J. Org. Chem. 1994, 59, 720.
Keywords: O-H -> O-SiMe2tBu --- Selenoxide-Ei -> Allyl-OR --- Claisen-Enol ether --- HWE -> EnoateEster --- Epoxide+Selenol --- Furst-Plattner diaxial --- Epoxidation, peracid --- Dehydrobromination -> Enoate
Reagents: SiMe2tBu-Cl --- MeSeAlMe2 --- NaOMe --- Epoxide --- HSe-Ph --- BF3·OEt2 --- Pertrifluoroacetic acid --- Rh2(OAc)4 --- LiNiPr2 --- Formaldehyde --- NaSePh --- Dioxirane --- Diazophosphonate --- Imidazole

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