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Total synthesis of Capnellene:
Reference: Paquette, L. A.; Stevens, K. E. Can. J. Chem. 1984, 62, 2415
Keywords: Ozonolysis --- Allyl-OH -> Enone --- Nazarov --- Mg-Vinyl+Enal --- ConjAdd Enone --- Li-Alkynyl+Ketone --- Rupe --- Cu-Vinyl+Enone --- ConjAdd Enone --- Aldol-K -> Enone --- Hydrogenation-Enone --- Wittig-methyl
Reagents: LiCuMe2 --- Alkynyl-Li --- HCO2H --- H2SO4 --- Vinyl-MgX --- CuI --- O3 --- Me2S --- Hydroxide, potassium --- H2, Pt --- Ph3P=CH2 --- KOtBu --- HCO2H --- Vinyl-MgX --- MnO2 --- P2O5 --- MeSO3H

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